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STRUCTURE AND PROPERTIES OF Ni22Cr10Al1Y COATINGS DEPOSITED BY THE VACUUM PLASMA SPRAY PROCESS
Mihailo R. Mrdak
Research and Development Center IMTEL Communications a.d.,
Belgrade, Republic of Serbia,
e-mail: [email protected],
ORCID iD: http://orcid.org/0000-0003-3983-1605
https://dx.doi.org/10.5937/vojtehg65-11904
FIELD: Chemical Technology ARTICLE TYPE: Original Scientific Paper ARTICLE LANGUAGE: English
Summary:
In this study, the aim was to deposit layers of the Ni22Cr10Al1Y coating using the vacuum plasma spray process to protect gas turbine engine components from oxidation and high-temperature corrosion. The coating can significantly affect the properties of the substrate because it forms a composite together with the substrate. The type of the coating deposition process and coating heat treatment, together with the substrate, significantly affect its resistance to high temperature creep. Ni22Cr10Al1Y powder was deposited with a vacuum plasma spray system of the Plasma Technik - AG company using the control panel A-2000 and the plasma gun F4. The coating deposited on the substrate of INCONEL X-750 alloy was thermally treated at 1100°C for 2 hours in a protective atmosphere of argon. The particle morphology was tested by scanning electron microscopy.The microhardness of layers was tested by the HV03 method and the bond strength was tensile tested, in accordance with the standard Pratt & Whitney. The microstructure of the deposited coating layers was examined under a light microscope. Coating etching was done by mixing 2.5ml of nitric acid HNO3 with 7.5ml of hydrofluoric acid HF. The microstructure of the etched coating before and after heat treatment, as well as the thickness of the diffusion zone, were analysed under a light microscope, based on which the coating quality was later assessed.
Keywords: vacuum, substrates, structural properties, plasmas, layers, coatings.
ACKNOWLEDGEMENT: The author is thankful for the financial support from the Ministry of Education and Science of the Republic of Serbia (national project TR 34016).
Introduction
The components of hot sections, such as gas turbine blades, have to withstand various stresses and severe environmental conditions at the operating temperatures of 900°C to 1000°C. The structures of alloys for producing hot sections are developed with optimum mechanical properties and MCrAlY coatings to provide the resistance of hot sections to high-temperature oxidation and hot corrosion (Mrdak, 2016, pp.1-25). In recent years, MCrAlY alloys have been widely used while vacuum plasma spraying (VPS) is the leading process used for depositing coatings on hot sections such as blades which are exposed to aggressive gases at high temperatures. MCrAlY coatings have been extensively studied in recent years; they have shown good properties and adequate oxidation resistance to hot corrosion (Wang, et al, 2002, p.70), (Mrdak, et al, 2015, pp.337343). There are two basic systems of coatings used on gas turbines to improve the resistance to hot corrosion and high-temperature oxidation, in order to prolong the working life of components. These are diffusion coatings and diffusion coatings coated with ceramic coatings. The Ni22Cr10Al1Y coating is used on components such as blades and other gas turbine parts as the protection against hot corrosion and high-temperature oxidation up to 1100°C (Material Product Data Sheet, 2012, Nickel Chromium Aluminum Yttrium (NiCrAlY) Thermal Spray Powders, Amdry 9624, DSMTS-0102.0, Sulzer Metco). The chemical composition of the Ni22Cr10Al1Y coating should be compatible with the substrate material to reduce inter-diffusion during operation. Aluminum is an element which protects Ni alloys from oxidation up to 1200°C by forming oxide phases a-Al2O3 on the coating surface. The microstructure of vacuum plasma sprayed Ni22Cr10Al1Y coatings consists of the Y-Ni and p-(NiAl) phases (Feuerstein, et al, 2008, pp. 199-213), (Padture, et al, 2002, pp.280-284). In the microstructure, there are also present Y'-(Ni3Al) precipitates in Y-Ni(Cr) grains (Ma, et al, 2010, pp.1518-1529). The Y'-(Ni3Al) precipitates in the M22Cr10Al1Y alloy provide better mechanical properties at temperatures below the solvus temperature, which is typically between 800 and 980°C (Achar, et al, 2004, pp.272-283), (Ma, et al, 2010, pp.1518-1529), (Mendis, Hemker, 2008, pp.255-258). The phases existing in the coating in the etched condition differ by color. The light gray regions in the coating microstructure are Y-Ni(Cr) grains which contain y'-Ni3Al precipitates, and the p-NiAl phase is dark gray. The differences in the microstructure between the APS and the VPS coatings are caused by higher temperatures of vacuum plasma spraying which increase the cohesive strength of lamellae and reduce the amount of oxygen in the environment,
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thereby preventing oxidation of molten particles. In the coating layers, there are no oxides of the types: a-Al2O3, Cr2O3, NiO and NiCr2O4, which occur in coatings deposited by the APS process (Mrdak, 2012, pp.182-201), (Mrdak, 2013, pp.26-47). When MCrAlY coatings are applied, it is known that there is an interaction between MCrAlY coatings with the substrate, which is negligible during the thermal spraying in comparison with coatings in exploitation. The thermal stability of sprayed coatings is decreased with increasing the working temperature of the gas turbine. The inter-diffusion degradation becomes important with the temperature increase. The interaction between the coating and the substrate of superalloys was tested by the author (Gómez-Acebo, et al, 2004, pp.237-251), (Dahl, et al, 2006, pp.pp.73-78), (Yuan, et al, 2014, pp.63-69), (Liu, et al, 2015, pp.63-69). The coating diffusion provides enrichment of the substrate surface with aluminum and chromium and a higher tensile bond strength. After the VPS deposition of MCrAlY coatings, thermal treatment is applied. The aim of the thermal treatment of the deposited coating with the substrate is to strengthen the coating by thermal precipitation of fine intermetallic Y'-Ni3Al compounds in the grains of solid Y-Ni(Cr) solution and the grains of the p-NiAl phase which increase the resistance of the coating to high-temperature creep together with the substrate. Due to diffusion bonding, the tensile bond strength of the coating significantly increases. The diffusion coating-substrate bonding occurs in the temperature range of 900 -1150°C. Examinations have shown that the microstructure of the MCrAlY coating thermally processed at 1000°C for 1 hour and then cooled with argon to the room temperature for 15 min consists of a y- solid solution rich in Ni, Co and Cr, which contains the dispersed phases of p-NiAl and y'-(Ni,Cr)3 (Funk, et al, 2011, pp.2233-2241), (Tang, et al, 2006, pp.94-106). In case of the Ni22Cr10Al1Y coating, vacuum deposited on the substrate of the 1N738LC nickel alloy, and after thermal processing in vacuum at a temperature of 1100°C for 2 hours, its microstructure shows the presence of fine globular particles of the p-NiAl phase (dark gray) and uniformly distributed in the matrix of Y-Ni(Cr) + Y'-Ni3Al which is light gray (Funk, et al, 2011, pp.2233-2241). Due to the diffusion of Al and Cr from the coating in the substrate, the coating/substrate interface shows a diffusion zone consisting of the light gray Y-Ni(Cr) matrix that contains Y'-Ni3Al precipitates of the deposited p-NiAl compounds (in black). Because of the diffusion of chemical elements from the substrate, the lower layers of the coating contain the elements Ni and Ti which build fine Y'-Ni3(Al,Ti) precipitates with aluminum (Itoh, Tamura, 1999, pp.476-483), (Gómez-Acebo, et al, 2004, pp.237-251), (Dahl, et al, 2006, pp.73-78).
The aim of this study was depositing a vacuum plasma sprayed (VPS) coating of the Ni22Cr10Al1Y alloy for the protection of gas turbine engine components against high-temperature corrosion and oxidation. In order to increase the resistance of the coating to high-temperature creep together with the substrate, thermal treatment was performed at 1100°C for 2 hours in a protective atmosphere of argon. The aim was to thermally deposit fine precipitates of Y'-Ni3Al (which strengthen the coating) into the grains of the solid solution Y-Ni(Cr) and the grains of the p-NiAl phase. After the thermal treatment, the mechanical properties of the coatings in the deposited condition were analyzed as well as the microstructure of the layers of the coatings in the deposited condition. The coating quality was assessed afterwards.
Materials and experimental details
Coatings were produced from AMDRY 9624 powder which protects the substrate from high temperature oxidation and hot corrosion at temperatures t < 1050°C (Material Product Data Sheet, 2012, Nickel Chromium Aluminum Yttrium (NiCrAlY) Thermal Spray Powders, Amdry 9624, DSMTS-0102.0, Sulzer Metco).
Figure 1 - (SEM) Scanning electron micrography of Ni22Cr10Al1Y powder particles
Рис. 1 - (SEM) Электронная микрография частиц порошка Ni22Cr10Al1Y Слика 1 - (SEM) Скенинг електронска микрограф^а честица праха Ni22Cr10Al1Y
NiCrAlY powder is a nickel alloy with 22wt.%Cr, 10wt.%Al and 1wt.%Y with a range of powder particle granulation of 11 - 37^m. For the powder production, the vacuum furnace melting technique was used as
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well as gas atomization of liquid melt with inert argon gas. The produced powder particles are homogeneous and spherical, Figure 1.
For microhardness testing and evaluation of the coating microstructure, the base was made of steel (X15Cr13 EN10027), thermally unprocessed, with the dimensions: 70x20x1.5mm. For testing the coating bond strength, the base was made of the same steel with the dimensions: 025x50 mm (Turbojet Engine - Standard Practices Manual PN 582005, 2002, Pratt & Whitney, East Hartford, USA). For testing the coating microstructure after heat treatment, the samples were made of an INCONEL X-750 alloy with the dimensions: 20x10x5 mm.
The mechanical properties of the layers were examined using the microhardness method HV03 and their bond strength was examined with tensile testing (Turbojet Engine - Standard Practices Manual PN 582005, 2002, Pratt & Whitney, East Hartford, USA). The morphology of powder particles was examined by the SEM method. The microstructure of the coating layers in the deposited state and after heat treatment in the etched state was tested with light microscopy. The coating etching was done by mixing 2.5ml of nitric acid HNO3 with 7.5ml of hydrofluoric acid HF.
Ni22Cr10Al1Y powder was deposited at low pressure with a vacuum plasma spray system of the Plasma Technik AG company. The control panel A-2000 and the plasma gun F4 were used for the powder deposition. Powder deposition was done with a mixture of plasma gases Ar/H2. Before powder deposition, the surface of the INCONEL X-750 alloy substrate was cleaned and pre-heated with a transferred arc at a temperature of 850°C. Table 1 presents the VPS parameters for cleaning the substrate surface and depositing Ni22Cr10Al1Y powder. The thickness of the coating deposited on the substrates ranged from 150-200 ^m. The coating deposited on the substrate of INCONEL Alloy X-750 was thermally treated at 1100°C in a protective atmosphere of argon for 2 hours.
Table 1 - Vacuum plasma spray parameters Таблица 1 - Параметры ваккумного плазменного напыления Табела 1 - Вакуум-плазма-спре] параметри
Parameters Values
Cleaning arc Spraying
Plasma current, I (A) 500 700
Plasma Voltage, V (V) 65 58
Primary plasma gas flow rate Ar (l/min) 50 50
Secondary plasma gas flow rate He (1),H2(2) (l/min) 10 (1) 8 (2)
Carrier gas flow rate (l/min) -- 3
Powder feed rate (g/min) -- 40
Parameters Values
Cleaning arc Spraying
Stand-off distance (mm) 270 270
Chamber pressure (mbar) 25 150
Nozzle diameter (m m) 8 8
Speed of the gun (mm /s) 20 250
Results and discussion
The mean value of the microhardness of Ni22Cr10Al1Y layers was 198 HV03. The lower value of the microhardness of the VPS Ni22Cr10Al1Y coating compared to the APS coating is caused by the absence of oxygen in the vacuum chamber, which prevents oxidation of molten particles in the deposition process. Low microhardness values confirm that in the coating deposited at low pressure there are not present a-Al2O3, Cr2O3, NiO and NiCr2O4 oxides which increase the value of the microhardness of coatings deposited at atmospheric pressure (Mrdak, 2012, pp.182-201). Besides the absence of oxidation in vacuum, low pressure of Ar inert gas allows preheating of the substrate up to 850°C, which leads to a substantial increase in adhesive bond strength. Tests have shown that the VPS-Ni22Cr10Al1Y coating has a bond strength of 84 MPa. Preheating the substrate and a low pressure of inert gas in the vacuum chamber further increase the coating density by eliminating micro pores and unmelted particles, as confirmed by the analysis of the coating microstructure on the light microscope. It is known that oxides and micro pores on the lamellae boundaries weaken the inter-lamellar bond, ie. cohesive strength and adhesion strength of the coating bond. Tensile strength testing has established that the failure mechanism was purely adhesion at the substrate / coating interface.
Figure 2 shows the microstructure of the VPS-Ni22Cr10Al1Y coating. The qualitative analysis showed that the substrate/ coating interface cannot be noticed because of cleaning and pre-heating the substrate surface with a transferred arc. The substrate/coating interface does not show defects such as: discontinuity of deposited layers, micro and macro cracks, micro and macro pores and separation of the coating from the base. The coating is dense and in the coating layers there are no: oxide lamellae, micro pores, precipitates, and unmelted particles. To see the microstructure of the coatings in the deposited state, Figure 3 shows a photomicrograph of the coating in the etched state. In the VPS Ni22Cr10Al1Y coating,
oxides and micro-cracks are completely suppressed, which resulted in an even and uniform deposition of layers.
Figure 2 - (OM) micrograph of the vacuum plasma sprayed Ni22Cr10Al1Y coating Рис. 2 - (ОМ) микрография вакуумного плазменного напыления Ni22Cr10Al1Y Слика 2 - (OM) Микрограф^а вакуум-плазма напрскане превлаке Ni22Cr10Al1Y
Figure 3 - (OM) Etched microstructure of the vacuum plasma sprayed Ni22Cr10AI1Y coating Рис. 3 - (ОМ) Поврежденная микроструктура покрытия, нанесенного вакуумным плазменным напылением Ni22Cr10AI1Y Слика 3 - (OM) Нагризена микроструктура вакуум-плазма напрскане превлаке Ni22Cr10AI1Y
Due to high temperature of the substrate and a complete melting of the layer deposited with the previously deposited layer, the lamellar microstructure in the coating completely disappeared. Coating etching makes two phases recognizable in the microstructure, one of which is light gray and the other is dark gray. The main phase of the coating (light gray) is the solid solution Y-Ni(Cr), which provides coating ductility and contains fine y'-Ni3Al precipitates while the dark gray p-NiAl phase provides resistance to oxidation (Funk, et al, 2011, pp.2233-2241). The coating microstructure
shows more regular melting of powder particles in vacuum relative to the atmospheric pressure.
Figure 4 shows a photomicrograph of a largely magnified coating to see the coating microstructure more clearly.
Figure 4 - (OM) Etched microstructure of the vacuum plasma sprayed Ni22Cr10AI1Y coating Рис. 4 - (ОМ) Поврежденная микроструктура покрытия, нанесенного вакуумным плазменным напылением Ni22Cr10Al1Y Слика 4 - (OM) Нагризена микроструктура вакуум-плазма напрскане превлаке Ni22Cr10AI1Y
Light gray regions of the solid Y-Ni(Cr) solution with Y'-Ni3AI precipitates are clearly seen as well as the dark gray region of the p-NiAl phase. The substrate/coating interface shows one unmelted powder particle of 25^m which is fully united with the deposited coating layers. The presence of the unmelted particle did not affect the formation of pores in the coating around it.
After heat treating the coating in vacuum in order to strengthen the deposited layers by thermal precipitation of intermetallic Y'-Ni3Al compounds, the coating is more homogeneous with respect to the deposited state (Figure 5). Homogeneity is a consequence of the increased solubility of Al in the y phase at a temperature of 1100 °C. During the heat treatment of Al and Ti, y' intermetallic compounds Ni3(Al,Ti) are formed with Ni from the substrate, thus enhancing the coating and increasing its resistance to high temperature creep, together with the substrate.
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Figure 5- (OM) Etched microstructure of the Ni22Cr10Al1Y coating after heat treatment at 1100°C/2 hours Рис. 5 - (ОМ) Поврежденная микроструктура покрытия Ni22Cr10Al1Y после термической обработки при 1100oC/2часа Слика 5 - (OM) Нагризена микроструктура превлаке Ni22Cr10Al1Y после термичког третмана на 1100°C/2 сата
After heat treatment under vacuum at a temperature of 1100 °C for 2 hours, the microstructure of the Ni22Cr10Al1Y coating shows globular particles of the p-NiAl phase (dark gray), evenly distributed in the Y-Ni(Cr) + Y'-Ni3Al matrix (light gray) (Funk, et al, 2011, pp.2233-2241). It is clearly visible that an inter-diffusion zone is formed on the inter-surface. Because of the dominant diffusion of Al and Cr from the coating into the substrate, a zone enriched with the p-(NiAl) phase was formed on the interface in the substrate. The diffusion layer was formed of the NiCr matrix (light gray) and the deposited p-NiAl compounds (black). Because of the diffusion of Al into the substrate, the Al content is reduced in the coating. Substantial precipitates of the p-NiAl phase are woven in the diffusion zone which is in the base of the INCONEL X-750 alloy. Also, Ti from the substrate diffuses into the lower layers of the coating where it participates with Al in the formation of intermetallic Y'-Ni3(Al,Ti) compounds (Itoh, Tamura, 1999, pp.476-483), (Gómez-Acebo, et al, 2004, pp.pp.237-251). The thickness of the diffusion zone formed of the Y-Ni(Cr) solid solution with precipitates and the p-(NiAl) phase on the coating / substrate interface is 20^m.
Conclusion
In this paper, vacuum plasma spraying is used to deposit Ni22Cr10Al1Y coating layers. The paper analyzes the mechanical properties and the microstructure of the coatings in the deposited state and after thermal treatment of the coating at 1100 °C in a protective atmosphere of argon for 2 hours. The following was concluded:
The VPS Ni22Cr10Al1Y coating had a mean microhardness value of 198HV0.3. The value of the VPS Ni22Cr10Al1Y microhardness is lower compared to the same coating deposited at atmospheric pressure due to the low pressure of Ar inert gas in the vacuum chamber, which prevented the oxidation of molten particles in the deposition process.
The tensile bond strength value of the VPS Ni22Cr10Al1Y coating deposited in vacuum was 84 MPa and is higher than the bond strength of the same coating deposited at atmospheric pressure. The tensile bond strength is higher because inter-lamellar oxides and micro pores are completely suppressed in the coating, which has led to higher inter-lamellar strength and stronger adhesion of the coating to the substrate.
The microstructure of the Ni22Cr10Al1Y coating in the deposited state after etching in the reagent consists of the basic phase of the solid solution of chromium in nickel Y-Ni(Cr) (light gray) which contains fine precipitates of Y'-Ni3Al and the p-NiAl phases (dark gray). The mirostructure of the Ni22Cr10Al1Y coating is homogeneous after heat treatment in vacuum. In the microstructure of the etched coating there are globular particles of the p-NiAl phase (dark gray) evenly distributed in the base of the Y-Ni(Cr) + y'-Ni3Al coating (light gray). At the interface, a 20^m-thick inter-diffusion zone was formed in the substrate. Because of the dominant diffusion of Al and Cr from the coating in the substrate, the zone enriched with the p-(NiAl) phase is present in the substrate at the interface. The diffusion layer is formed from the Y-Ni(Cr) matrix (light gray) and the deposited p-NiAl compounds (black). Because of diffusion, Ti from the substrate in the lower coating layers participates with Al in the formation of intermetallic Ni3(Al,Ti) compounds. The formed diffusion layer and deposited intermetallic compounds in the coating increase its resistance to high-temperature creep along with the substrate.
The VPS Ni22Cr10Al1Y coating has a much better structure and mechanical properties compared to the properties of the coating deposited at atmospheric pressure and as such can successfully be applied in hot
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sections of turbojet engines to protect them against high-temperature oxidation and corrosion.
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СТРУКТУРА И СВОЙСТВА ПОКРЫТИЯ 1\Л22Сг10А11У НАНЕСЕННОГО МЕТОДОМ ВАКУУМНОГО ПЛАЗМЕННОГО НАПЫЛЕНИЯ
Михаило Р. Мрдак
Центр исследований и развития А.О. «ИМТЕЛ коммуникации», г. Белград, Республика Сербия
ОБЛАСТЬ: химические технологии
ВИД СТАТЬИ: оригинальная научная статья
ЯЗЫК СТАТЬИ: английский
Резюме:
В данной статье описан процесс нанесения покрытия Ni22Cr10Al1Y вакуумным плазменным напылением для защиты деталей газотурбинного двигателя от оксидирования и высокотемпературной коррозии. Покрытие может оказать значительное воздействие на свойства субстрата, так как вместе с ним создает композит.
Течение процесса депозиции покрытия и режим термической обработки с субстратом значительно влияют на стойкость слоев покрытия к высокотемпературной ползучести.
Нанесение порошка Ni22Cr10Al1Y произведено аппаратом вакуум плазменного напыления от производителя Plasma Technik - AG, включающим пульт управления А-2000 и плазматрон F4. Покрытие нанесено на субстрат сплава INCONEL X-750, затем произведена двухчасовая техническая обработка при 11000C в защитной среде аргона. Морфология частиц порошка испытана методом оптической микроскопии. Анализ механических характеристик покрытия проведен на основании испытаний микротвердости методом HV03 и прочности соединений методом растяжения. Микротвердость покрытия соответствуют требованиям стандартов Pratt & Whitney. Микроструктура слоев нанесенного покрытия испытана методом световой микроскопии. Повреждения покрытия вызваны раствором азотной кислоты 2.5ml HNO3 с 7.5ml плавиковой кислоты.
Анализ микроструктуры повреждений покрытия до и после термической обработки, а также толщины диффузной части проведен методом световой микроскопии, на основании результатов анализа дана оценка качества покрытия.
Ключевые слова: вакуум, субстраты, структурные свойства, плазма, слои, покрытие.
СТРУКТУРА И CBOJCTBA ПРЕВЛАКЕ Ni22Cr10Al1Y ДЕПОНОВАНЕ ВАКУУМ-ПЛАЗМА-CnPEJ ПРОЦЕСОМ
Михаило Р. Мрдак
Истраживачки и разводи центар ИМТЕЛ Комуникаци|е а. д., Београд, Република Срби]а
ОБЛАСТ: хеми]ске технологи]е
ВРСТА ЧЛАНКА: оригинални научни чланак
иЕЗИК ЧЛАНКА: енглески
Сажетак: 5
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Цил> рада jecme да се вакуум-плазма-cnpej процесом
депонуу слojeeu превлаке Ni22Cr10Al1Y за заштиту компоненти "
гасних турбина од оксидацие и високотемпературне корозие. â
Превлака може знатно утицати на своjства субстрата, jер <л
заjедно са субстратом формира композит. Врста процеса |
депозицие превлаке и режим термичке обраде превлаке са субстратом битно утичу на шену отпорност на високотемпературно пузане. Депоноваше праха Ni22Cr10Al1Y ура^ено jе вакуум-плазма-спреj системом фирме Plasma Technik го - AG ко\и користи командни пулт А-2000 и плазма пиштоъем Е F4. Превлака депонована на субстрату од легуре INCONEL X-750 термички jе обращена на 110CrC у траjашу од 2 сата у заштитноj Е атмосфери аргона. Морфологиа честица праха испитана jе методом скенинг електронске микроскопие. Испитиваша g микротврдоПе слоjева ранена су методом HV03 и чврстоПе споjа <и методом испитиваша на затезаше, ща су била у складу са стандардом Pratt& Whitney. Микроструктура слоjева превлаке у депонованом сташу испитана jе на светлосном микроскопу. Нагризаше превлаке ранено jе мешашем азотне киселине 2,5 ml о HNO3 са 7,5 ml флуороводоничне киселине HF. Анализа микроструктуре нагризене превлаке пре и после термичке обраде, као и дебл>ина дифузионе зоне, изведена jе на светлосном микроскопу, на основу чега jе оцешен квалитет превлаке. g
К^учне речи: вакуум, субстрати, структурна сво]ства, плазма, сло]еви, превлаке. <;
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Paper received on / Дата получения работы / Датум приема чланка: 26. 09. 2016. cn
Manuscript corrections submitted on / Дата получения исправленной версии работы / — Датум достав^а^а исправки рукописа: 05. 12. 2016.
Paper accepted for publishing on / Дата окончательного согласования работы / Датум коначног прихвата^а чланка за об]ав^ива^е: 07. 12. 2016.
© 2017 The Author. Published by Vojnotehnicki glasnik / Military Technical Courier (www.vtg.mod.gov.rs, BTr.M0.ynp.cp6). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/rs/).
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© 2017 Автор. Опубликовано в «Военно-технический вестник / Vojnotehnicki glasnik / Military о
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