CC BY
39
40
AZERBAIJAN CHEMICAL JOURNAL № 2 2019
UDC 543.4:542.61:546.72
SPECTROPHOTOMETRY DETERMINATION OF IRON(III) WITH 3-((2-HYDROXYPHENYL)DIAZENYL)PENTADIONE-2,4 AND DIANTIPYRYLMETHANE
A.Y.Abiyeva, F.V.Kuliyeva, Kh.J.Nagiyev, A.Q.Babayev, F.M.Chyragov
Baku State University [email protected] Received 10.10.2018
The complex formation of iron(III) with 3-((2-hydroxyphenyl)diazenyl)pentadione-2,4 and diantipyrylme-thane was investigated by spectrophotometry method and highly selective method of determination of its microamounts in natural objects established. It's found that at pH 2.0-2.5 in the presence of diantipyryl-methane Fe(III) forms with reagent intensively colored mixed-ligand complex Fe(III)-R-DAM with the ratio of components 1:2:1. During formation of mixed-ligand complex bathochromic shift and hyper-chromic effect are observed compared to binary complex. The optimum conditions of formation of same and mixed-ligand complexes of Fe(III) were determined and the main spectrophotometric characteristics calculated. By spectrophotometry method stability constants of complexes are determined and found that mixed-ligand complex Fe(III)-R-DAM has high stability: lgP(Fe-R)=5.76±0.10; lgP(Fe-R-DAM)=14.65±0.26. The new highly selectivity spectrophotometry method for the determination of iron(III) has been developed and applied for the determination of its quantity in volcanic mountain rocks.
Keywords: iron(III), 3-((2-hydroxyphenyl)diazenyl)pentadione-2,4, diantipyrylmethane, volcanic mountain rock.
https://doi.org/10.32737/0005-2531-2019-2-40-43
In connection with the higher chemical and analytical characteristics compared to the corresponding appropriate complexes, the formation reactions of the various complexes are widely used in analytical chemistry, especially in spectrophotometry analysis [1-3]. These reactions have higher sensitivity and selectivity and in some cases they are able to directly determine the trace components in samples of complex composition [4, 5]. We have so far proposed a number of methods for the determination of various metal ions, which have high analytical characteristics, including methods based on the formation of different ligand complexes of iron(III) [6-9]. In the present study, the complex formation of iron(III) with 3-((2-hydroxyphe-nyl)diazenyl)pentadione-2,4 was investigated by a spectrophotometric method and a new selective method was developed for its determination in samples of complex composition.
Experimental part
Reagents and solutions. The standard solution of 1.0-10-1 M iron(III) was prepared by solving the calculated sample weight of iron metal in chloride acid (1:1) with addition of nitric acid [10]. The working solution of 2.0-10-3
M iron(III), used in the work has been prepared by rinsing standard solution with distilled water before use.
The 2.0-10- M solutions of diantipyrylmethane (DAM) and 3-((2-hydroxyphenyl)diaze-nyl)pentadione-2,4 (R), used in the study were prepared by solving their calculated sample weights in ethanol. Acetate-ammonia buffer solutions (pH 3-11) and HCl fiksanal (pH 0-2) were used to create a suitable acidity environment. All used reagents were of analytical grade.
Equipment. The Lambda-40 spectrophotometer of "Perkin Elmer" company equipped with a computer and the KFK-2 photoelectric calorimeter were used for spectrophotometry research in UV and visible regions. The optical density of the solutions was measured using /=1.0 cm thick tubes. The acidity of the solutions was controlled by using pH-121 pH-meter with glass electrode.
Methods. Various amounts of iron(III) salt with a final concentration of 0.34 to 4.48 mkg/ml were poured in measuring tubes with a volume of 25 ml, 2.5 ml of 2.0-10-3 M reagent solution and 1.5 ml of 2.0-10-3 M diantipyryl-methane solution were added and diluted to
A3EPEAH#^AHCKHH XHMHHECKHH ^YPHA-T № 2 2019
mark with 0.01 M HCl (pH 2.0) solution. Analogically, the "blind practice" (R+DAM) solution was prepared. The optical density of the prepared solutions was measured at KFK-2 photoelectric calorimeter in /=1.0 cm thickness in the background of the "blind experience" at wavelength X=490 nm.
Results and discussion
Iron(III) interact with 3-((2-hydroxyphe-nyl)diazenyl)pentadione-2,4 in pH 1.0-8.0 acidity medium and forms intensive color complex compound at maximum light absorption X=434 nm (Figure 1). The complex has the maximum yield at pH=4.5-5.0 acidic environment (Figure 2). Reagent has a maximum absorption of light in an acidic environment (pH 1.0-7.0) at wavelength X=382 nm. The addition of diantipyrylmethane to the Fe(III)-R complex solution creates a different ligand complex Fe(III)-R-DAM, resulting in a batochromic shifting and hyperchromic effect in the absorption spectrum, as well as the maximum shift of the maximum yield to a more acidic environment. The maximum light absorption of the Fe(III)-R-DAM different ligand complex corresponds to the wavelength X=476 nm (Figure 1). pHopt=2.0-2.5. The absorption spectra of the complexes were also studied in the background of the "blind experience" (R and R+DAM) because the color of the reagent and complexes various depending on the acidity of
A 0.8 -
0.60.40.2 -
the environment. It has been established that the same and different ligand complexes of iron have maximum light absorption in the background of "blind experience" at X=490 nm.
In order to determine the optimal conditions for formation the effects of components concentration, time and temperature on the complex formation were investigated. It has been established that for the formation of the Fe(III)-R complex the 2.0-10-4 M of reagent and for the formation of the Fe(III)-R-DAM complex the 2.0-10-4 M of reagent and 1.2-10-4 M concentration of diantipyrylmethane is required. The optical density of the same ligand complex remains constant at 2.5-10.0, of the different ligand complex at about 2.5-10.0 and 1.5-8.0 times higher of concentrations of the reagent and diantipyrylmethane respectively. Despite the fact that both iron(III) complexes are formed by mixing components solutions they differ from each other in solution by stability. The Fe(III)-R-DAM complex maintains its optical density at a temperature of up to 800C during one day, while the Fe(III)-R complex is stable in the solution for 2 hours and up to 600 temperature.
The ratio of components in the composition of the studied complexes was determined by the methods of equilibrium shift, relative output of Starik-Barbanel and izomolar series [11].
AA 0.5
0.4 0.30.2 0.1-
400 450 500 550 600 650 nm
Fig. 1. Absorption spectra of iron(III) complexes in pHopt acidic medium: 1 - R, 2 - Fe(III)-R, 3 - Fe(III)-R-DAM; CFe=8.0-10-5 M, CR=2.0-10-4 M, CDAM=1.2-10-4 M; Lambda-40, /=1.0 cm.
1 2
6
8 pH
Fig. 2. Dependence of light absorption of iron(III) complexes on pH on the background of the "blind experience": 1 - Fe(III)-R, 2 - Fe(III)-R-DAM; CFe=8.0-10-5 M, CR=2.0-10-4 M, Cdam=1.2-10-4 M; KFK-2, /=1.0 cm.
42
A.Y.ABIYEVA et al.
The results of all three methods showed that the ratio of components in the composition of the Fe(III)-R complex was 1:2 and in Fe(III)-R-DAM complex 1:2:1 (Table 1). The number of H+ ions allocated during the formation of complexes was determined by Astakhov method and the results of the ratio of the components in their composition were confirmed [12].
Stability constants of complexes were determined by the spectrophotometric method and the Fe(III)-R-DAM different ligand complex was found to have a higher stability: lgP(Fe-R)=5.76±0.10; lgP(Fe-R-DAM)= 14.65 ± 0.26.
During the determination of the iron in the form of Fe(III)-R and Fe(III)-R-DAM complexes, the Ber law is observed into its range of 0.45-4.48 and 0.34-4.48 mg/ml respectively. The equations of the established graphs using the least squares method have been determined [13]. Fe(III)-R; A=(0.110±0.005>C+(1.43± 0.08>10-3, Fe(III)-R-DAM; A=(0.410±0.009>C+(6.20± 0.27>10-4.
The molar absorption coefficient of the Fe(III)-R and Fe(III)-R-DAM complexes at a wavelength Xopt is equal to (3.10 ± 0.06)-10 and (6.00 ±0.10>103, respectively.
The effect of the foreign ions and masking agents for determination of iron(III) in the form of the same and different ligand complexes was studied and the determination method on the basis of the complex formation was found to have higher selectivity. To determine Fe(III)-R-DAM as a complex, do not interfere a 5000fold amounts of alkali, alkaline-earth metals and
rare earth elements; 1000-fold of Mg(II), Co(II), Ni(II), Mn(II), Pb(II), Cd(II), Zn(II), Cu(II), Cr(III); 600-fold of Al(III), Ga(III), in(IIl), Ti(IV), Th(IV), V(V), U(VI) and 50fold of Zr(IV), Hf(IV), Mo(VI) and W(VI) ions.
The developed method was applied for determining the amount of iron in volcanic mountain rocks of the Lesser Caucasus, taken from Kalbajar region of Azerbaijan Republic.
A sample of 5.0 grams of rock was weighted on analytical scale and dissolved by heating in 20 ml of HF + 15 ml HCl + 5 ml HNO3 mixture to form a paste in graphite chamber. The obtained paste was processed until the complete sublimation of the residue of hydrogen-fluoride with 4-5 ml of HNO3 at a temperature of 60-700C. The remaining residue was then dissolved in distilled water and insoluble part separated filtered through filter paper. The separated solution was transferred to a 50 ml measuring tube and diluted to mark with distilled water. Different aliquot parts were removed from the prepared solution and transferred to a 25 ml measuring tube and by adding a reactive and diantipyrylmethane solution in the amount corresponding to the maximum yield of the Fe(III)-R-DAM complex was diluted to mark with 0.01 M HCl (pH 2.0) solution. The optical density of the prepared solutions was measured in the order described in the method and the amount of iron was determined according to the graduated degree graph. The results of determination are given in Table 2.
Table 1. Chemical and analytical characteristics of iron(III) complexes with 3-((2-hydroxyphenyl)diazenyl)pentadione-2,4
Complex pHopt ^max, nm Дк, nm eT03 CR/CVe CDAM/CFe The ratio of components in the composition lgP The interval of obeying to Beer's law, mkg/ml
Fe-R 4.5-5.0 434 52 3.10±0.06 2.5-10 1:2 5.76±0.10 0.45-4.48
Fe-R-DAM 2.0-2.5 476 94 6.00±0.10 2.5-10 1.5-8.0 1:2:1 14.65±0.26 0.34-4.48
Table 2. Determination of iron in volcanic mountain rocks («=5, P=0.95)
Sample Quantity of components according to passport,% Found Fe, %
I TiO2 - 0.75; Fe2O3 - 4.52 (Fe - 3.164); FeO - 0.88 (Fe - 0.684); CaO - 5.88; MgO - 1.50; P2O5 - 0.72; MnO - 0.02; K2O - 4.00; Na2O - 5.40; In2O3 - 0.01; Ga2O3 - 0.00945; Sc2O3 - 0.01; SeO3 - 0.05; REE - 0.70; H2O - 0.29; SiO2 -75.26055 3.846±0.114 0.026
II TiO2 - 0.70; Fe2O3- 4.68 (Fe - 3.276); FeO - 0.74 (Fe - 0.575); CaO - 5.88; MgO - 1.10; P2O5 - 0.71; MnO - 0.02; K2O - 3.92; Na2O - 5.60; In2O3 - 0.01; Ga2O3 - 0.0102; Sc2O3 - 0.01; SeO3 - 0.05; REE - 0.30; H2O - 0.13; SiO2 -76.1398. 3.866±0.102 0.022
АЗЕРБАЙДЖАНСКИЙ ХИМИЧЕСКИЙ ЖУРНАЛ № 2 2019
References
1. Pilipenko A.T., Tananoiko M.M. Raznoligandnye i raznometallnye kompleksy i ikh primenenie v analiticheskoi himii. M.: Himiia, 1983. 224 s.
2. Savvin S.B., Chernova R.K., Shtykov S.N. Poverkh-nostno-aktivnye veshchestva. M.: Nauka, 1991. 251 s.
3. Umland F., Iansen A., Tirig D., Viunsh G. Kompleks-nye soedineniia v analiticheskoi himii. M.: Mir, 1975. 531 s.
4. Liu Xian-Guo, Yang Wen-Hua, Wang Ping. Spectro-photometric determination of gallium SDM-phenyl-fluorone and cetytrimethylammonym bromide. Chin. J. Spectrosc. Lab. 2002. V.19. No 3. P. 317-319.
5. Filik Hayati, Tutem Esma. Use of the molybdenum thiocyanate-rhodamine 6G ternary complex for specrtophotometric determination molybdenum without extraction. Anal. chim. acta. 2004. V. 505. No 1. P.77-82.
6. Giulliarli U.A., Nagiev KH.D., Gambarov D.G., Chyragov F.M. Vzaimodeistvie tcirko-niia(IV) s 2,3,4-trigidroksifenilazo-5'-sulfonaftalinom v pri-sutstvii diantipirilmetana i ego gomologov. Zhurn. analit. himii. 2006. T. 61. No 6. C. 604-607.
7. Nagiev Kh.D., Espandi F.E., Alieva R.A., Giulliarli U.A., Chyragov F.M. Opredelenie mikrokolichestv
zheleza v fruktakh. Analitika i kontrol. 2013. T. 17. № 1. C. 107-111.
8. Abiyeva A.Y., Ismiyev A.I., Nagiyev Kh.D., Chyragov F.M., Askerov R.K. Synthesis, crystal structure and research opportunities of 2,4-diacetyl-3-(3'-nitrophenyl)-5-hydroxy-5-methylcyclohexanone. New Materials, Compounds and Applications. 2018. V. 2. No 1. P. 22-27.
9. Abiyeva A.Y., Aliyeva R.A., Nasibli A.H., Ismiyev A.I., Nagiyev Kh.J. Co-operation of iron(III) with 2,4-diacethyl-3-phenyl-5-methyl-5-hidroxihexanon in the presence of diantipyrylmethane and dian-tipyrylphenylmethane. East Eur. Scientific J. Chemia. 2016. No 6. C. 139-143.
10. Korostelev P.P. Prigotovlenie rastvorov dlia himi-ko-analiticheskikh rabot. M.: Nauka, 1964. 261 s.
11. Bulatov M.I., Kalinkin N.P. Prakticheskoe ruko-vodstvo po fotometricheskim metodam analiza. L.: Himiia, 1986. 432 s.
12. Astahov K.V., Verinikin V.B., Zimin V.I., Zverko-va A.A. Spektrofotometricheskoe izuchenie kom-pleksoobrazovaniia nekotorykh redkozemelnykh elementov s nitrilouksusnoi kislotoi. Zhurn. Neor-gan. ximii. 1961. T. 6. C. 2069-2076.
13. Batuner L.M., Pozin M.E. Matematicheskie metody v himicheskoi tekhnike. L.: Him. lit., 1963. 638 s.
DOMiRlN(in) 3-((2-HiDROKSiFENiL)DiAZENiL)PENTADiON-2,4 УЭ DiANTiPiRiLMETANLA
SPEKTROFOTOMETRlK TOYiNi
A.Y.Abiyeva, F.V.Quliyeva, X.C.Nagiyev, O.Q.Babayev, F.M.^iraqov
Diantipirilmetan i§tirakinda damirin(in) 3-((2-hidroksifenil)diazenil)pentadion-2,4-la kompleks этэ1э gatirmasi spektrofotometrik metodla tadqiq edimi§ va tabii obyektlarda onun mikromiqdannin tayini ügün yüksak seciliya malik metodika i§lanib hazirlanmi§dir. Müayyan edilmi§dir ki, diantipirilmetan i§tirakinda damir(III) reaktivla pH 2.0-2.5 tur§uluqlu mühitda Fe(III):R:DAM komponentlari nisbati 1:2:1 olan intensiv rangli qan§iqliqandli kompleks amala gatirir. Qan§iqliqandli kompleksin amala galmasi udma spektrinda eynilandli kompleksin udma spektri ila müqayisada batoxrom sürü§ma va hiperxrom effektla mü§ayiat olunur. Eyni- va qan§iqliqandli komplekslarin optimal amala galma §araiti müayyan edilmi§ va asas spektrofotometrik xarakteristikalan hesablanmi§dir. Spektrofotometrik metodla komplekslarinin davamliliq sabitlari tayin edilmi§ va Fe(III)-R-DAM qan§iqliqandli kompleksinin daha yüksak davamliliga malik oldugu müayyan edilmi§dir: lgß(Fe-R)=5.76±0.10; lgß(Fe-R-DAM)=14.65±0.26. Damirin(III) tayinin ügün yüksak segiciliya malik yeni spektrofotometrik metodika i§lanib hazirlanmi§ va i§lanmi§ metodika vulkanik dag suxurlarinda onun mikromiqdannin tayini ügün tatbiq edilmi§dir.
Agar sözlar: d3mir(III), 3-((2-hidroksifenil)diazenil)pentadion-2,4, diantipirilmetan, vulkanik dag suxuru.
СПЕКТРОФОТОМЕТРИЧЕСКОЕ ОПРЕДЕЛЕНИЕ ЖЕЛЕЗА(ПГ) С 3-((2-ГИДРОКСИФЕНИЛ)ДИАЗЕНИЛ)ПЕНТАДИОНОМ-2,4 И ДИАНТИПИРИЛМЕТАНОМ
А.Ю.Абиева, Ф.В.Кулиева, Х.Д.Нагиев, А.К.Бабаев, Ф.М.Чырагов
Спектрофотометрическим методом исследовано комплексообразование железа(Ш) с 3-((2-гидроксифенил)ди-азенил)пентадионом-2,4 в присутствии диантипирилметана и разработана высокоселективная методика определения его микроколичеств в природных объектах. Установлено, что при pH 2.0-2.5 в присутствии диантипирилметана железо(Ш) с реагентом образует интенсивно окрашенный смешанно-лигандный комплекс Fe(ni)-R-,nAM с соотношением компонентов 1:2:1. При образовании смешанно-лигандного комплекса наблюдаются батохромные сдвиги и гиперхромный эффект в спектре поглощения по сравнению с бинарным комплексом. Установлены оптимальные условия образования и рассчитаны основные спектрофотометрические характеристики однородного и смешанно-лигандного комплекса железа(Ш). Спектрофотометрическим методом определены константы устойчивости комплексов и установлено, что смешанно--лигандный комплекс Fe(nii-R-,nAM обладает большой устойчивостью: lgß(Fe-R)=5.76±0.10; lgß(Fe-R-DAM)=14.65±0.26. Разработанная нами новая методика применена для определения микроколичеств железа(Ш) в вулканогенных горных породах.
Ключевые слова: железо(Ш), 3-((2-гидроксифенил)диазенил)пентадиона-2,4, диантипирилметан, вулканогенные горные породы.
