CC BY
9For citation: Hu Zekui, Mei Shunqi, Alexey Guryev, Burial Lygdenov. Principle and metal
surface application of electroless Ni-B plating // Grand Altai Research & Education —
Issue 1 (19)'2023 (DOI: 10.25712/ASTU.2410-485X.2023.01) — EDN: https://elibrary.ru/jhxnto
UDK 544.654.2
Principle and metal surface application
of electroless Nl-B plating
Hu Zekui1, Mei Shunqi1, Alexey Guryev1'2, Burial Lygdenov1'3
1 Hubei Digital Textile Equipment Key Laboratory, Wuhan Textile University, Wuhan, China 2 Zhejiang Taitan Co., Ltd, Zhejiang Xinchang, China 3 Zhejiang Xinchang Sanxiong Bearing Co., Ltd, Zhejiang Xinchang, China E-mail: [email protected] ; [email protected]
Abstract. Ni-B plating is widely used in textile, aerospace, automotive, ship and other fields due to its excellent characteristics such as uniform thickness, high hardness, anti-wear, corrosion resistance and self-lubrication. In this paper mainly introduces the principle and application of electroless Ni-B plating, and finally looks forward to the development trend of electroless Ni-B plating. It is believed that the future of electroless plating can be developed towards the direction of excellent electroless NiB plating solution and plating method with strong adaptability and high compatibility, so that a solution or metal surface treatment method can be applied to a variety of metals.
Keywords: electroless Ni-B; principle; application
шш^ш ni-B ттшттт
mm1, rnjm1, ^шт^шшш^1'2, шштт^шш*1'3
E-mail: [email protected] ; [email protected]
rnМ: Ni-в йШ, rnrnrn, МШЙ,
Пт№ШЯ, да, &ШШШ. Ni-B Ш
мшдапш, й^мшт^шшяшмй^мт
^ШШМ, МШМШШШNi-B шш, шшшш, ш-шш
^Ш Ni-B; ШЖ; Ш
0 ЩЙ
жтш^-, ^шш&айЛйш^ш (en), чшш (cvd), шшш (lc) щ [1]. кш Ni-в шт
тш, Шй, ЙШ, Ш^Щ^ЁЙШ^, тшхтш, тш, ш, тщ, тшш, т$тя, п^, шщмшттг%м№ [2].
яхяшт^ш Ni-в штштшшшш, x^mitxt Ni-в ш тшшшттшшштж, ттшшшш Ni-в шт^ш ш&шшшттш.
1 ШШ Ni-в ШШ&МШ
1946 Brenner m Riddle МЙЛ, М^Т^Ш^ШШШ^ (Electroless Plating) [3]. 1954 ^
m ^шшшшштшш®, мяш, дещшш^ш тштшпм. 1968 тшшшшшштш, &шшштш
тт 20 ш 70 m иттвшшш^т^х^г, x ттш&ъ-штшш&тш. ЙЛВШШ-^ЙШ, ушйш
тшштттшня 20 ш 80
Ш, тшжштшшшшш [4]. 21 шшшшш ш&тйш [5]. тш, »п#ш»мощ,
2 ^ш Ni-в штшж 2.1
жшп^я, тшшт, т^, ^ттшшишшшм, ^w, м2+, й^шшт
тттш&шштшт, Ш2 ш.
4Ni2++BH4-+8OH--►B(OH)4-+4Ni+4H2O (2-1)
Ж-^тЭДМШШЙ^ 1:1, Й^ШШШ^:
2Ni2++4H2O+2BH4--► 2Ni+B+B(OH)4-+3H++^H2 (2-2)
mi
1) SM; 2) Ä 3) 4) iPÄg; 5) »^S Figure 1. Electroless plating device 1) Lanyard; 2) Plating solution; 3) Substrate; 4) Heating device; 5) Mixing device
Figure 2. Principle of electroless plating
2.2
шм, mm ph ^^
M [5], ЯЯж,
шж^тшш, тшш,
шшщ.
^^М: ттмшш, мш&ш, ^шшт^
ш. № ъгм,
адш^мшш^ш. № шшнэд,
PH iM^MO: гМ^ШШ pH,
т {ьтштяшж^мтт
Table 1. Main composition of electroless nickel-boron plating solution
(g/L)
ТЖ-ПИ 20-30 Ошибка! Источник ссылки не найден. -Ошибка! Источник ссылки не найден.
6 Ошибка! Источник ссылки не найден.
йШ адшш 0.4-1.2 Ошибка! Источник ссылки не найден.
адш^ 0.5-2 Ошибка! Источник ссылки не найден.
1 Ошибка! Источник ссылки не найден.
60-120 Ошибка! Источник ссылки не найден.
7 Ошибка! Источник ссылки не найден.
20-40 Ошибка! Источник ссылки не найден.
шш 0.11 Ошибка! Источник ссылки не найден.
0.02 Ошибка! Источник ссылки не найден.Ошибка! Источник ссылки не найден.Ошибка! Источник ссылки не найден.
0.015 Ошибка! Источник ссылки не найден.
mm 1 Ошибка! Источник ссышки не найден. -Ошибка! Источник ссышки не найден.
nwrn^ 20-40
pH il^O ^шШ рн, ттшжж^шж 40 Ошибка! Источник ссылки не найден.
РЖ Ошибка! Источник ссылки не найден.
3 Ni-B
3.1 Ni-B
Х^ФШй^Ж, ШШ Ni-B ШЖШШЙ^Г^. [16]
Ni-в шшмттш
МШ\. F. Buibui [17] йЗД^Ф, ^ШШШШМШЯ^ aisi 304
штп L9
wan y [is] тш
ЖМ PTFE Ш^ШШЙ aisi 52100 Ni-B
3.2 ШШ&ШШ Ni-B
M. Vijayanand [19]
(Ш, ШМ 7075-T6
r. Petro [20] т№$7-шмт'\тттш&жш
AZ91D т AM50
V. Vitry [21] Al-Cu-Mg
(95%Ar+5%H2) ЧШТШШ&Ш,
E. Correa [15] ШШ&ШМКШШШШШ, Ni-B Ш
тштшшшм.
3.3 Ш&ШШ Ni-B
S. Ziyuan [7]
[22] тжшшшшя
±Ш7ШШ, М«п#±, Ni-B М
% [13] жшШ^ХЙЙШЖ (^жтттшт)
fAmMttm.
Ni-B , mm, ^^
m m m, ^M, ^»it^m
im
Mft^nM*!^. 4
Ni-B 0
ft, sm^ffffMMMRTOMiffJ
Itt^^ff Ni-B «, ff^I^m
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