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Microwave-Hydrothermal Synthesis of Nb-doped BaTiO3 Nanoparticles under Various Conditions
A. Khanfekr*, M. Tamizifar, R. Naghizadeh
Department of Metallurgical and Materials Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran, e-mail: [email protected]
Tetragonal BaTiO3 powders were synthesized by the microwave-hydrothermal (MH) method. The effects of the reaction time and temperature on the MH synthesis were investigated. Typical experiments were performed with a solid state reaction for the system BaTiO3+Nb2O3 at a high temperature. In the MH method, at a shorter time and lower temperature, the rate of the formation of tetragonal BaTiO3 and of the growth of particles went down substantially. The microwave heating can be very fast and uniform through a self-heating process that results from the direct absorption of the microwave energy in the reaction mixture. The synthesis of Nb-doped BaTiO3 has been investigated under MH conditions in the temperature range of 120-180°C for 1-3 hours using Ci6H36O4Ti, BaH2O2 • 8H2O, and NbCl5 as Ba, Ti and Nb sources, respectively. In the phase evolution studies, the X-ray diffraction measurements and Raman spectroscopy were employed. The Transmission Electron Microscope and the Field Emission Scanning Electron Microscopy images were taken for the detailed analysis of the grain size, surface, and morphology. The MH method was applied for the synthesis of Nb-doped BaTiO3 via provided advantages of the fast crystallization and decreased crystallite size. The nucleation rate should have been high because of a high heating rate in microwave heating processes.
Keywords: ceramics, chemical synthesis, microwave-hydrothermal synthesis, crystal structure, perovskites.
УДК 544.463:544.526.5
INTRODUCTION
Perovskite-type oxides have the general formula of ABO3 in which A is a rare earth or alkaline earth metal and B is a transition metal. Applications of this group of materials in electrochemistry [1, 2], oxygen separation membranes [3], chemical sensors for the detection of humidity [4], alcohol [5], gases such as oxygen [6] and hydrocarbon [7], and of nitric oxide [8] for over 30 years are the basis for understanding their mixed conductivity by both ion and electron migrations and their high nonstoichio-metric composition. Since there is a strong dependence of ferroelectric properties on the grain size and compositional aspects, the microstructural control has become very important [9]. BaTiO3-based positive temperature co-efficient (PTC) thermistors are widely used as over-current protectors, motor starters for refrigerators and air conditioners, temperature sensors, and so on [10-14]. The hydrothermal method is attractive for synthesizing BaTiO3 powder because the combined effects of the solvent, temperature, and pressure on the ionic reaction equilibrium can stabilize desirable products while inhibiting formation of undesirable compounds. Hydrothermal synthesis also makes it possible to prepare BaTiO3 powder in a single processing step and does not require elaborate apparatuses or expensive reagents However, just like in most convectional hydrothermal processes, BaTiO3 powders prepared by the
microwave-hydrothermal (MH) synthesis at temperatures below 200°C were cubic or pseudo cubic, though the tetragonal structure is thermodynamic, stable at room temperature. To convert hydrothermal BaTiO3 from the cubic to tetragonal shape, heating at temperatures over 1000°C is required, which always leads to the grain growth and particle aggregation. Therefore, a direct generation of tetragonal BaTiO3 through the hydrothermal process is of a considerable interest, both in science and in industry [13-15].
It has been reported [15, 16] that the nanostruc-tural and dielectric features of nano-sized Nb-doped BaTiO3 powders vary sensitively with their size and preparation conditions. To the best of our knowledge, there are few reports on the doped BaTiO3 metal-semiconductor transition on Nb doping, in particular. Sintered bulk ceramics of Nb-doped BaTiO3 show the semiconducting behavior when doped with a small amount of Nb, but when Nb concentration exceeds 0.4-0.5 mol %, the specimens revert to the insulator state. The main reason for the increase of resistivity when the donor concentration exceeds a certain value is the fact that the compensation mechanism changes from one that mainly involves electrons to one that primarily involves cation vacancies [15-18]. In the present paper, we analyze the effect of incorporating different amounts of Nb on the microstructural development of BaTiO3. A particular emphasis is placed in
© Khanfekr A., Tamizifar M., Naghizadeh R., Электронная обработка материалов, 2015, 51(5), 23-28.
the morphology and composition of secondary phases.
Compared to the traditional solid-state reaction and other wet-chemical routes (including sol-gel processing, oxalate route, and homogeneous precipitation), the hydrothermal method is low-cost and convenient to prepare BaTiO3 nanoparticles without a following high temperature calcination process [16-21]. In order to produce powders of a desired size and shape, several researchers investigated a variety of hydrothermal conditions, such as the pH value, Ba/Ti ratio, reaction temperature as well as various precursors [21-25]. Though many efforts have been pulled to prepare BaTiO3 particles, still there is insufficient knowledge about the effects of doping and solvent type on the size and shape under hydrothermal conditions. A number of authors [21-25] have synthesized BaTiO3 by the MH method at T below 200°C but the MH processing of Nb-doped BaTiO3 has not been reported so far with other authors. We succeeded in our initial efforts to synthesis of Nb doped BaTiO3 in the temperature of 150°C for only 2 hours [26]. Therefore in this work, we have investigated the effect of incorporating Nb on the properties of BaTiO3 via the MH conditions in the temperature range of 120-180°C for 1-3 hours.
EXPERIMENTAL
The MH reactions were performed to synthezise Nb-doped BaTiO3. For more details, please, refer to our earlier manuscript [26]. The system was heated in the temperature range of 120-180°C for 1-3 hours. The obtained powders were characterized by the X-ray diffraction (XRD), with the Cu-Ka radiation in the 29 range from 20° to 60° and Raman spectroscopy (spectral range 80-3500 cm-1). Microstructural characterization was performed by the field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM).
RESULTS AND DISCUSSION
Figure 1 shows the XRD patterns for the MH Nb-doped BaTiO3 powders prepared in the temperature range of 120-180°C for 1-3 hours. From the XRD patterns it can be considered that the sample prepared at 120°C for 1 h (MH-120-1) forms a pattern similar to an amorphous product, but when the time and temperature rise, the BaTiO3 powder becomes a structurally uniform crystalline with high crystallinity. Except the sample prepared at 120°C for 2 h (MH-120-2), the nanoparticles were pure perovskite Nb-BaTiO3, without some intermediate carbonate phase that was observed at 29 28° and 34° in the sample MH-120-2 [16]. The presence of BaCO3 can be accounted for either by an incomplete
reaction or by the presence of carbonate in the Ba alkali source, or by the reaction of CO2 in air [14].
It is clearly seen that with the enhancement of time and temperature, the maximum of the peak shifts towards higher 29 values and the intensity of the peaks grows. According to the investigations of some researchers [28, 29], the shift of peaks can be related to the displacements of barium. In the tetragonal phase, the optimization of the crystal geometry of BaTiO3 after doping with Nb is attained by the impurity-outward displacements of barium. The movements are mainly in the ab plane while the motion along the c axis is practically negligible. In the sample synthesis at the highest time and temperature, we have the highest intensity.
When the size of BaTiO3 powders is below 1 ^m, the full-width at half-maximum (FWHM) of the corresponding (110) XRD peaks becomes larger and such broadening leads to the overlapping of two peaks located close to each other [14, 23, 27]. The structural changes associated with the phase transition usually have a large effect on the Raman spectrum. The XRD studies produce data that are consistent with an increasingly cubic structure at smaller particle sizes, not distinguishing between an average and a local structure. Thus, the XRD patterns reveal the characteristics of cubic BaTiO3 without certain peak splitting while the Raman results have supported the existence of a tetragonal symmetry at small dimensions, even though it was not discernible by XRD. The Raman spectra for the obtained Nb-BaTiO3 ceramic powder samples are presented in Figure 2. The peaks at 185, 305, 518 and 715 cm-1 are characteristics of the tetragonal BaTiO3 The peaks at 191 and 392 cm-1 are assigned to TiO2 [30-33].
The dependence of the degree of the tetragonal fraction on the particle size has been extensively investigated for BaTiO3 [23, 30]. A variety of explanatory models were proposed and researchers reported that the tetragonal distortion decreased when the particle size was below 1 ^m [23, 24]. Thus, a reasonable explanation for a larger tetrago-nality in the sample synthesized at 180°C is the fact that the particles grow faster under MH conditions and at higher temperatures.
The FE-SEM images of Nb-BaTiO3 powders prepared at 150°C and 180°C for 2 h are shown in Fig. 3 and Fig. 4, respectively. It is evident that the powder prepared at 150°C consists of ultrafine, well dispersed uniform particles with the average size of 45 nm, the particle size being distributed from 40 to 50 nm. Whereas for the powders synthesized at 180°C, the average particle size increases substantially to the average size of 90 nm, with the particle size distribution being from 70 to 110 nm.
Fig. 1. XRD patterns of Nb-BaTiO3 nanoparticles at different time and temperature: (Up) Zoom in (110) and (200) planes (Down).
Fig. 2. Raman spectra of hydrothermal nanosized Nb-BaTiO3 powders.
Fig. 3. Nb-BaTiO3 powder prepared at 150°C for 2 h.
In the MH process, the microwave radiation can be absorbed by BaTiO3 particles and smaller BaTiO3 particles will dissolve more quickly. According to the dissolution/recrystallization mechanism, this will lead to larger particles growing faster with time and temperature [23, 32, 33].
The MH synthesis leads to the homogeneous nucleation of a large number of tiny stable Nb-BT particles, which further grow uniformly; the primary Nb-BT particles form agglomerates [24, 28].
Fig. 4. Nb-BaTiO3 powder prepared at 180°C for 2 h.
The crystallite size of the particles was calculated with the XRD using the Scherrer equation as in [35]:
D = K (1)
" B,e cos 9'
where Dv is the crystallite size, K isa constant whose value is 0.9, X is the X-ray wavelength; the width of the peak, Bsize, was determined as the full width at half-maximum. The crystallite size was 52 and 95 nm for the Nb-BaTiO3 powder prepared at
150°C and 180°C for 2 hours, respectively. These results are in good agreement with the FE-SEM data, too.
Fig. 5. Nb-BaTiO3 powders prepared at 150°C for 1 h.
Fig. 6. Nb-BaTiO3 powders prepared at 180°C for 1 h.
The TEM images taken to estimate the size of the particles and the morphology of the particles for powders prepared at 150°C and 180°C for 1 h are shown in Fig. 5 and Fig. 6, respectively. The decreased crystal size in MH-150-2 might be related to a high heating rate in MH processes. At the microwave frequency of 2.45 GHz, the changes of plus/minus in the waveguide occur 2450 million times in 1 s. Depending on the characteristics of the dielectric, it tends to modify the alternating electric field through structural changes. When a water sample is placed in a reactor and subjected to an alternating electric field, the electric deviation (electric dipole) of the water molecule tends to follow the alternating electric field. However, since water consists of clusters of water molecules through hydrogen bonding, not all can follow the alternating electric field. The result is the dielectric heating of water by the irradiating microwaves. Moreover, as for the case of ions in solution, the Joule heating takes place by space-charge polarization. When microwave heating, an electrolyte-water solution dielectric heating, and the Joule heating occur simultaneously, compared with pure water, then exothermic efficiency becomes remarkably high. Accordingly, dielectric heating by orientation polarization of water and resistance heating by the Joule process are enhanced in electrolyte - water media. This rapid homogeneous heating, not possible by convectional heating, provides a uniform nucleation [36].
CONCLUSIONS
The present investigation shows that nanosized particles of Nb-BaTiO3 powder can be crystallized via a rapid and cost-effective MH process without the temperature gradient and uneven nucleation and growth of particles of various sizes. The MH can be
very fast and uniform through a self-heating process that arises from the direct absorption of the microwave energy in the reaction mixture. When microwave heating an electrolyte-water solution dielectric heating and the Joule heating occur simultaneously compared with pure water, and thus exothermic efficiency becomes remarkably high. Accordingly, dielectric heating by orientation polarization of water and resistance heating by the Joule process are enhanced in electrolyte - water media. This rapid homogeneous heating, not possible by convectional heating, provides a uniform nucleation. Because of a homogeneous nucleation, uniformly-sized particles can be prepared. But according to the dissolu-tion/recrystallization mechanism, both the extent of tetragonality and the particle size increase quickly with time and temperature. When the reaction temperature goes down, the formation of the tetragonal structure and growth of particles are slowed down substantially, showing a critical effect of the reaction temperature on the MH processing of tetragonal BaTiO3.
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Received 13.08.14 Accepted 24.11.14
Реферат
Порошки тетрагонального БаТЮ3 были синтезированы СВЧ-гидротермальным методом (СГ). Были исследованы эффекты времени реакции и температуры на СГ синтез. В экспериментах осуществляли твердотельную реакцию в системе БаТЮ3 + №203 при высокой температуре. Скорость формирования тетрагонального БаТЮ3 и роста частиц при применении СГ метода с более коротким периодом обработки и при более низкой температуре существенно снизилась. СВЧ-нагрев может быть очень быстрым и однородным вследствие процесса саморазогрева в результате непосредственного поглощения СВЧ-энергии в реакционной смеси. Синтез БаТЮ3, легированного исследовали в условиях СГ-процесса в интервале температур 120-180°С в течение 1-3 часов с исполь-
зованием С16И3604Т1, ВаИ202'8И20 и №С15, как источники Ва, Т и соответственно. При исследовании эволюции фаз применяли рентгенодифракцион-ный метод и спектроскопию комбинационного рассеяния. Изображения, полученные методами трансмиссионной электронной и автоэмиссионной сканирующей электронной микроскопии, были использованы для детального анализа размера зерна, поверхности и морфологии. СГ метод был применен для синтеза ВаТЮ3, легированного №, с целью реализации преимуществ быстрой кристаллизации и уменьшения размера кристаллитов. Скорость зарождения кристаллитов должна быть высокой из-за высокой скорости нагрева в процессах СВЧ нагрева.
Ключевые слова: керамика, химический синтез, СВЧ-гидротермальный синтез, кристаллическая структура, перовскиты.
