CC BY
19
NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2016, 7 (3), P. 479-481
Magnetic field dependent resonant light scattering by magnetic spheres
in a magnetizable medium
Hem Bhatt
Shantilal Shah Engineering College, Sidsar, Bhavnagar. 364060, India [email protected]
PACS 47.65.Cb, 42.25.Fx, 42.68.Ay, 41.20.Jb DOI 10.17586/2220-8054-2016-7-3-479-481
The anisotropy factor is a parameter from which one can determine preferential forward and backward light scattering. In the present study, we have calculated anisotropy factor (cos 0) as a function of magnetic field for magnetic spheres in a magnetic medium. We have noticed resonances in (cos 0) which indicate preferential enhanced scattering in forward and backward directions. Anisotropy factor is analyzed for various size parameters. The study clearly indicates that scattering can be modulated by means of size parameter of magnetic spheres as well as magnetic field. We have further confirmed the result by studying forward and backward intensity as a function of magnetic field. Resonances noticed in the intensity are in good agreement with the previous argument. This observation can be useful for the magnetic field dependent directional scattering and novel magneto-photonic devices. Keywords: mie resonances, scattering, magnetic colloids, magneto-photonics. Received: 23 January 2016. Revised: 8 March 2016
1. Introduction
In the recent past, the high energy and working efficiency of photonic devices have attracted researchers to design and study materials in which light transport can be tuned by controlling some external parameters. Recently, a new frontier has also emerged with a goal of controlling light transport by means of interference in artificially engineered optical materials and metamaterials [1-6]. Remarkable progress has been noted in the fabrication of nanophotonic structures with many novel properties [7]. The disorder present and the magnetic tenability have made magnetically polarizable fluids preferable for many applications like optical switches, modulators, filters and gratings, etc. [8,9]. Light transport and optical study of resonant behavior have been studied in disordered magnetic media along with coherent backscattering and light localization [10-13]. But very few have used magnetic tuning of magnetic spheres to predict theoretical and experimental photonic effects [14-16]. Several groups are working on single and multiple scattering by magnetic scatterers in non-magnetic medium [17-19]. Our recent studies have shown some unusual light transport in ferrocolloids in presence of external magnetic field [20]. This study reflects effect of magnetic field Mie resonance by magnetic spheres dispersed in magnetic nanofluids and its impact on light transport in magnetic colloids.
2. Theory
We consider a magnetizable sphere of arbitrary size parameter a(= 2nrA) with 'r' being the radius of the particle and A is free space wavelength of incident light and refractive index ms surrounded by a magnetizable medium like a ferrofluid. According to Mie theory, scattered intensities for the two orthogonalized linearly polarized states are given by i\ = |Si(ms, a, 0)|2 and i2 = |S2(ms, a, 0)|2, i\ and i2 correspond to the scattered field components, perpendicular and parallel to the scattering plane (i.e. plane formed by the direction of applied field and the propagation direction). The scattering coefficients S1(ms, a, 0) and S2(ms, a, 0) are defined by:
2n +1
Si(ms,a, 0) = y] ———) [a„n„(cos 0) + b„r„(cos 0)] , z—' n(n + 1
n=1 v
2n +1
S2 (ms, a, 0) = y] ——— [a„r„ (cos 0) + b„n„ (cos 0)] , z—' n(n + 1)
n=1 v '
where Mie coefficients a„ and bn for magnetic sphere are defined by [20]:
= - m^(^n(q)
" (£)&(a) - (a) ,
b = - M^(mn(a)
" (a) - (a) ,
480
Hem Bhatt
and nn (cos 0) and Tn(cos 0) are the partial derivative of the Legendre polynomials and angle 0 is the angle between the forward and scattering directions. —s and ms are respectively magnetic permeability and refractive index of the scatterers with respect to the surrounding medium. ^n and (n are respectively Riccati Bessel and Hankel functions. Prime denote derivative with respect to arguments. The arguments of Riccati-Bessel and Hankel functions are given by a = 2nr/X and 3 = (msa).
In the present case however, the medium is magnetically active and both —m and ms may depend on the applied magnetic field. Ferrofluids usually contain nanomagnetic particles of magnetic oxides like Fe2O3 or Fe3O4 hence we shall assume that at optical frequencies —m ~ 1. The refractive index of the ferrofluid may be expressed as mf = mTOL(£) + m0, where m0 is the refractive index at zero field and is the saturation value of the field
1 —H
dependent refractive index and the Langevin function L(£) = coth(£) - -, with £ = -— where u is the magnetic
£ kT
moment of the monodomain nanomagnetic particles of ferrofluid, H is the applied field; k and T are respectively the Boltzmann constant and absolute temperature of the medium [21]. Considering the ferrofluid as a magnetizable medium, the relative refractive index of the MMS will be given by mMMS = mscat/mf. Since mf depends on —H
£ = -—; mMMS will also depend on H. This will lead to the field dependence of the scattering parameters an, kT
bn, S1(ms,a, 0), S2(ms, a, 0) and i\ and i2.
Fig. 1. It shows the (cos 0) as a function of magnetic field for different values of size parameter ka. For ka = 30 large resonance is observed. The negative value suggests preferential backscattered intensity
3. Result and discussion
It is known that for micron sized dielectric spheres the incident light excites localized electromagnetic modes at the surface of spheres. Such modes may trap light near the surface of the sphere by repeated total internal reflections. Resonances in such systems are a consequence of the refractive index mismatch, or shape or size, and are called morphology-dependent resonance (MDR) [22].
In Fig. 1, the anisotropy factor (cos 0) is plotted as a function of the applied magnetic field for different size parameter ka. It is noted that for ka = 0.5 no resonance is observed, it suggests that the system behaves as a Rayleigh scatterer. For ka = 30 maximum resonant behavior is observed, but for ka = 100 the resonance is not so strong. This suggests that for critical size parameter, the resonance is pronounced. The fact that (cos 0) can assume negative values indicates a predominant backward scattering. This is quite unusual in the case of scattering by non-magnetic spheres. The reason for the appearance of a preferential backscattering configuration in the small particle limit is the significant contribution given by magnetic dipolar radiation in magnetic scattering. These resonances may produce a standing wave configuration within the spheres that can cause the delay in light transport in magnetic colloids, which can be tunable by external magnetic field.
Figure 2 (A and B) shows the resonance produced in the light transport for ~ 3 — m size magnetic spheres suspended in magnetic nanofluids (for forward and backscattered light) as a function of magnetic field. It should be noted here that at certain magnetic field values, the transmitted intensity becomes zero and generates magnetically induced stop band of light.
Magnetic field dependent resonant light..
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0 0.05 0.1 0.15 0 0.05 0.1 0.15
Field (T) Field (T)
Fig. 2. Variation of forward and backward scattering intensity as functions of magnetic field for a magnetizable micronsized sphere (MMS) having diameter 3 ^m suspended in magnetic nanofluids. Transmitted intensity exhibits magnetic field dependent resonant behavior
4. Conclusion
The present study has shown that an externally applied magnetic field induced morphological dependent resonance in a magnetizable sphere surrounded by magnetic nanofluids. This system exhibits resonance in forward as well as in backward direction. (cos в) as a function of magnetic field shows preferential backward scattering. Such resonance produces standing wave within the magnetic spheres and can cause delay in light transport. These properties of such a system are useful for the development of novel magneto-photonic devices.
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